(η6-IsopropylN-phenylcarbamate)(η5-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate acetone monosolvate

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(η6-Isopropyl N-phenyl­carbamate)(η5-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) tetra­phenyl­borate acetone monosolvate

The title complex, [Ru(C(10)H(15))(C(10)H(13)NO(2))](C(24)H(20)B)·C(3)H(6)O, is related to the analogous O-methyl complex. The average Ru-C distance to the penta-methyl-cyclo-penta-dienyl (Cp*) group is 2.19 (3) Å, and 2.21 (1) Å to the ortho, meta and para C atoms of the arene ring. The Ru-C(ipso) bond length of 2.272 (3) Å is significantly longer, reflecting movement of the Ru atom away from ...

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Rubrene endoperoxide acetone monosolvate

The title acetone solvate, C(42)H(28)O(2)·C(3)H(6)O [systematic name: 1,3,10,12-tetra-phenyl-19,20-dioxapenta-cyclo-[10.6.2.0(2,11).0(4,9).0(13,18)]icosa-2(11),3,5,7,9,13,15,17-octa-ene acetone monosolvate], is a photooxygenation product of rubrene (systematic name: 5,6,11,12-tetra-phenyl-tetra-cene). The mol-ecule bends at the bridgehead atoms, which are linked by the O-O transannular bond, wi...

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N,N′-Diphenyl­thio­urea acetone monosolvate

In the title compound, C(13)H(12)N(2)S·C(3)H(6)O, the phenyl rings of the thio-urea mol-ecule are in syn and anti positions in relation to the C=S bond. Two mol-ecules are connected by N-H⋯S=C hydrogen bonds into a centrosymmetric dimer. An additional N-H⋯O=C hydrogen bond to the acetone solvent mol-ecule and some weak C-H⋯π inter-actions reinforce the crystal structure.

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Bis(tetra­phenyl­phospho­nium) tetra­iodidomanganate(II) acetone monosolvate

The title compound, (C(24)H(20)P)(2)[MnI(4)]·(CH(3))(2)CO, prepared from the reaction of manganese powder, iodine and tetra-phenyl-phospho-nium iodide in acetone shows a tetra-hedral complex anion [Mn-I = 2.6868 (5)-2.7281 (4) Å and I-Mn-I = 104.011 (13)-116.164 (15)°], two tetra-phenyl-phospho-nium cations and one mol-ecule of acetone.

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Bis(2,6-dicarboxy­pyridinium) dichloride acetone monosolvate

The title compound, 2C(7)H(6)NO(4) (+)·2Cl(-)·C(3)H(6)O, crystallizes with two 2,6-dicarboxy-pyridinium cations, two chloride anions and one acetone mol-ecule in the asymmetric unit. The crystal structure is characterized by alternating cations and by Cl(-) anions, forming zigzag chains running along the a axis.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811031655